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1. chinaXiv:201904.00095 [pdf]

Real-Time Evolution of the Electron Clouds of Transition Metal Ions: Electron-Pairing Medium of Unconventional High Temperature Superconductors

Tege Zhou
Subjects: Physics >> Condensed Matter: Electronic Structure, Electrical, Magnetic, and Optical Properties

The electron-pairing mechanism in unconventional high temperature superconductors (HTS) has not been resolved. The author proposed that the electron-pairing medium of unconventional HTS is the change of the electron clouds of transition metal ions, which is analogous to the lattice vibration in conventional superconductors. Real-time evolution of the electron clouds of transition metal ions under excitations in La2Fe2As2O2, FeSe sheet, Fe2KSe2, CaCuO2, and HgBa2Ca2Cu3O8 was calculated by the time-dependent density functional theory (TDDFT). The characteristic frequency is about 90-250 meV, which is equivalent to the lattice vibration frequencies, showing that the change of the electron clouds of the transition metal ions can be the electron-pairing medium in unconventional HTS.

submitted time 2019-04-24 Hits11619Downloads1105 Comment 0

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