分类： 核科学技术 >> 核材料与工艺技术 提交时间： 2023-06-18 合作期刊: 《Nuclear Science and Techniques》
摘要： Poly[bis(phenoxyphosphazene)] (PBPP) and magnesium hydroxide (MH) are used as a flame retardant blend with low-density polyethylene (LDPE) for the nuclear cable. This study aims to investigate the effects of PBPP in MH-LDPE blend composites on flame retardance and electron beam irradiation. The structure, morphology, and properties of the blend composites irradiated by an electron beam to different absorbed doses were characterized. The results indicated that PBPP provides lubrication during processing. As the PBPP content in the blend increases the melt flow rate at 20 phr MH, meaning the material is easier to process. The higher the PBPP content, the higher the limiting-oxygen index. The elongation at the break of the PBPP containing composites (at 50 phr MH) was evidently higher than the non-PBPP ones at different absorbed doses by electron beam irradiation. The thermogravimetric analysis results indicated that the improved mechanical property, resulting from electron-beam irradiation, could be attributed to the consumption of PBPP.
分类： 核科学技术 >> 核材料与工艺技术 提交时间： 2023-06-18 合作期刊: 《Nuclear Science and Techniques》
摘要： Reversible addition-fragmentation chain transfer (RAFT) mediated grafting of acrylonitrile onto Polyethylene/Poly(ethylene terephthalate) (PE/PET) composite fibers was performed using -irradiation as the initial source at ambient temperature. Different initial concentrations of 2-cyanoprop-2-yl dithiobenzonate were used as the chain transfer agent. The kinetics of graft polymerization is in accordance with the living RAFT polymerization. The successful grafting of acrylonitrile is proved by Fourier transform infrared spectroscopy analysis. The results of monofilament tensile test show that mechanical properties of the fibers change slightly after grafting. Scanning electronic microscopy images of the fibers show that the surface of RAFT grafted fibers is smoother than that of fibers grafted conventionally.
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