分类： 核科学技术 >> 核材料与工艺技术 提交时间： 2023-06-18 合作期刊: 《Nuclear Science and Techniques》
摘要： Poly[bis(phenoxyphosphazene)] (PBPP) and magnesium hydroxide (MH) are used as a flame retardant blend with low-density polyethylene (LDPE) for the nuclear cable. This study aims to investigate the effects of PBPP in MH-LDPE blend composites on flame retardance and electron beam irradiation. The structure, morphology, and properties of the blend composites irradiated by an electron beam to different absorbed doses were characterized. The results indicated that PBPP provides lubrication during processing. As the PBPP content in the blend increases the melt flow rate at 20 phr MH, meaning the material is easier to process. The higher the PBPP content, the higher the limiting-oxygen index. The elongation at the break of the PBPP containing composites (at 50 phr MH) was evidently higher than the non-PBPP ones at different absorbed doses by electron beam irradiation. The thermogravimetric analysis results indicated that the improved mechanical property, resulting from electron-beam irradiation, could be attributed to the consumption of PBPP.
分类： 核科学技术 >> 核材料与工艺技术 提交时间： 2023-06-18 合作期刊: 《Nuclear Science and Techniques》
摘要： Reversible addition-fragmentation chain transfer (RAFT) mediated grafting of acrylonitrile onto Polyethylene/Poly(ethylene terephthalate) (PE/PET) composite fibers was performed using -irradiation as the initial source at ambient temperature. Different initial concentrations of 2-cyanoprop-2-yl dithiobenzonate were used as the chain transfer agent. The kinetics of graft polymerization is in accordance with the living RAFT polymerization. The successful grafting of acrylonitrile is proved by Fourier transform infrared spectroscopy analysis. The results of monofilament tensile test show that mechanical properties of the fibers change slightly after grafting. Scanning electronic microscopy images of the fibers show that the surface of RAFT grafted fibers is smoother than that of fibers grafted conventionally.
分类： 核科学技术 >> 核材料与工艺技术 提交时间： 2023-06-18 合作期刊: 《Nuclear Science and Techniques》
CHI Hong-Ying
LIU Xi-Yan
MA Hong-Juan
YANG Xiao-Juan
YU Ming
ZHANG Jian-Yong
WANG Min
LI Jing-Ye
Hiroyuki Hoshina
Noriaki Seko
摘要： Amino-type adsorbents (ATAs) were prepared by radiation-induced graft copolymerization of 4-hydroxybutyl acrylate glycidyl ether (HB) onto a polyethylene-coated polypropylene (PE/PP) duplex fiber of a non-woven fabric, and modified with different amines of ethylenediamine (EDA), diethylenetriamine (DETA), triethylenetetramine (TETA) and diethylamine (DEA). The adsorption behavior of uranyl ions onto the ATAs was studied in batch experiments. The effects of the contact time, initial concentration of the ions, temperature, and pH value. The salinity were investigated along with the adsorption kinetics and the adsorption isotherms. The kinetic experimental data followed the pseudo second-order kinetic model, and the adsorption isotherms correlated well with the Langmuir model. The ATAs showed good efficiency in adsorbing uranyl ions, with the best saturation adsorption capacity being 64.26 mg g-1 for ATA-DETA within 120 min. The temperature dependence of ATA-DETA was quite abnormal and the quickest behavior was obtained at 25 ℃. ATAs showed good adsorption capacity over a wide pH range of 4.08.5, and HCl could be used in the elution process. Salinity of the solution had great effect on the adsorption capacity, 3.5% salinity resulted in a 55% loss of capacity from ATA-DETA. The selectivity of ATA-DETA showed an order of: UO22+ Fe3+ > Zn2+ > VO3- > Co2+ > Ni2+.
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