分类： 核科学技术 >> 核科学与技术 提交时间： 2024-05-11
摘要： The Dynamics beamline (D-Line), which combines synchrotron radiation infrared spectroscopy (SR-IR) and energy-dispersive X-ray absorption spectroscopy (ED-XAS), is the first beamline in the world to realize concurrent ED-XAS and SR-IR measurements at the same sample position on a millisecond time-resolved scale. This combined technique is effective for investigating rapid structural changes in atoms, electrons, and molecules in complicated disorder systems, such as those used in physics, chemistry, materials science, and extreme conditions. Moreover, ED-XAS and SR-IR can be used independently in the two branches of the D-Line. The ED-XAS branch is the first ED-XAS beamline in China, which uses a tapered undulator light source and can achieve approximately 2.5 × 1012 photons/s•300 eV BW@7.2 keV at the sample position. An exchangeable polychromator operating in the Bragg-reflection or Laue-transmission configuration is used in different energy ranges to satisfy the requirements for beam size and energy resolution. The focused beam size is approximately 3.5 μm (H) × 21.5 μm (V), and the X-ray energy range is 5–25 keV. Using one- and two-dimensional position-sensitive detectors with frame rates of up to 400 kHz enables time resolutions of tens of microseconds to be realized. Several distinctive techniques, such as the concurrent measurement of in-situ ED-XAS and infrared spectroscopy, time-resolved ED-XAS, high-pressure ED-XAS, XMCD, and pump–probe ED-XAS, can be applied to achieve different scientific goals.
分类： 核科学技术 >> 辐射物理与技术 提交时间： 2023-12-22
摘要： The infrared microspectroscopy beamline (BL06B) is a phase II beamline project at the Shanghai Synchrotron Radiation Facility (SSRF). The construction and optical alignment of BL06B were completed by the end of 2020. By 2021, it became accessible to users. The synchrotron radiation infrared (SRIR) source included edge radiation (ER) and bending-magnet radiation (BMR). The extracted angles in the horizontal and vertical directions were 40 and 20 mrad, respectively. The photon flux, spectral resolution, and focused spot size were measured at the BL06B end station, and the experimental results were consistent with theoretical calculations. SRIR light has a small divergence angle, high brightness, and a wide wavelength range. As a source of IR microscopy, it can easily focus on a diffraction-limited spatial resolution with a high signal-to-noise ratio (SNR). The BL06B end station can be applied in a wide range of research fields, including materials, chemistry, biology, geophysics, and pharmacology.
分类： 光学 >> 量子光学 提交时间： 2023-02-19
摘要： Ultrasensitive terahertz sensing of highly absorptive aqueous solutions remains challenging due to strong absorption of water in the terahertz regime. Here, we experimentally demonstrate a cost-effective metamaterial-based sensor integrated with terahertz time-domain spectroscopy for highly absorptive water-methanol mixture sensing. This metamaterial has simple asymmetric wire structures that support multiple resonances including a fundamental Fano resonance and higher order dipolar resonance in the terahertz regime. Both the resonance modes have strong intensity in the transmission spectra which we exploit for detection of the highly absorptive water-methanol mixtures. The experimentally characterized sensitivities of the Fano and dipole resonances for the water-methanol mixtures are found to be 160 and 305 GHz/RIU, respectively. This method provides a route for readily available metamaterial-assisted terahertz spectroscopy for ultrasensitive sensing of highly absorptive chemical and biochemical materials with multiple resonances and high accuracy.
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