分类： 核科学技术 >> 裂变堆工程技术 提交时间： 2023-06-18 合作期刊: 《Nuclear Science and Techniques》
摘要： The rapid development of nuclear technology has led to more liquid organic radioactive wastes. Different from the regular aqueous radioactive wastes, these liquids possess a higher hazard potential and cannot be disposed through the conventional methods due to their radioactivity and chemical nature. Spent extraction solvent is a kind of common liquid organic radioactive wastes. In this work, tri-butyl phosphate (TBP), which is more difficult to degrade in the spent extraction solvent, was used as the model compound. Influences of reaction conditions on total organic carbon (TOC) removal and the volume percentage of each gas component under supercritical water oxidation (SCWO) were studied. The SCWO behaviors of spent extraction solvent simulants were studied under the optimal conditions derived from the TBP experiment. The SCWO experiments were studied at 400550 ℃, oxidant stoichiometric ratio of 0200%, feed concentration of 1.5%4% and pressure of 25 MPa for 1575 s. The results show that the TOC removal of the simulants was greater than 99.7% and CH4, H2 and CO were not detected at 550 ℃, 25 MPa, oxidant stoichiometric ratio of 150%, feed concentration of 3%, and residence time of 30 s.
分类： 核科学技术 >> 核材料与工艺技术 提交时间： 2023-06-18 合作期刊: 《Nuclear Science and Techniques》
CHEN Li-Fang
BIAN Xiao-Kai
HOU Zheng-Chi
LIU Zhong-Ying
QIN Qiang
PAN Ling
SHEN Li-Guo
SHI Liu-Qing
LU Xiao-Feng
摘要： Porous membranes were prepared using the phase inversion method from poly(vinylidene fluoride)-graft-poly(N-vinyl pyrrolidone) (PVDF-g-PVP) powders, which were synthesized via -ray induced graft polymerization (pre-irradiation). Chemical compositions, thermal behavior, morphology and hydrophilicity of the membranes were characterized by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, element analysis, thermalgravimetric analysis, differential scanning calorimetry, scanning electron microscopy and contact angle measurements, respectively. Permeation experiments were conducted to evaluate the water flux, and the dynamic BSA fouling resistance performances were investigated, too. All the experimental results indicate that the PVDF-g-PVP membranes demonstrate better separation performances over the pristine PVDF membrane.
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