分类: 物理学 >> 凝聚态:电子结构、电、磁和光学性质 提交时间: 2019-07-02
摘要: P. W. Anderson raised an important question in 2007: Is There Glue in Cuprate Superconductors? The author believes that the change of the electron clouds of ions is the glue in cuprate superconductors. The change of the electron clouds of the ions in the parent structure of the layered high-temperature superconductors CaCuO2 has been studied by the first-principles calculations. The electron clouds of Cu2+ and O2- ions change obviously under electric fields. It is also found, for the first time, the characteristic frequencies of the change of the electron clouds are 250 meV, 360 meV, and 100 meV, respectively, for the modes observed. The frequencies are low and close to that of lattice vibrations, indicating the change of the electron cloud of ions can be the electron-pairing medium in cuprate superconductors.
分类: 物理学 >> 凝聚态:电子结构、电、磁和光学性质 提交时间: 2019-04-24
摘要: The electron-pairing mechanism in unconventional high temperature superconductors (HTS) has not been resolved. The author proposed that the electron-pairing medium of unconventional HTS is the change of the electron clouds of transition metal ions, which is analogous to the lattice vibration in conventional superconductors. Real-time evolution of the electron clouds of transition metal ions under excitations in La2Fe2As2O2, FeSe sheet, Fe2KSe2, CaCuO2, and HgBa2Ca2Cu3O8 was calculated by the time-dependent density functional theory (TDDFT). The characteristic frequency is about 90-250 meV, which is equivalent to the lattice vibration frequencies, showing that the change of the electron clouds of the transition metal ions can be the electron-pairing medium in unconventional HTS.