分类: 物理学 >> 凝聚态:电子结构、电、磁和光学性质 提交时间: 2024-04-17
摘要: The identification of new materials with superconducting properties is the pursuit in the realm of superconductivity research. Here, excitedly, we show that the simplest salt daily used can be made a superconductor at normal pressure only by adjusting its stoichiometry of Na and Cl as Na3Cl at normal pressure based on first-principles calculations. This bulk stable abnormal Na-Cl stoichiometric crystal of 3:1, the first ‘magic’ ratio, includes metallic (Na) atoms in the core as well as hybridization of ionic and metallic bonding, facilitating the electron-phonon-coupling for superconductivity with a critical temperature Tc of 0.13 K. The flat bands and van Hove singularities near the Fermi level produce large densities of states, similar to H3S and LaH10, which is beneficial for the emergence of superconductivity. The crystal composed of with abnormal Na-Cl magic stoichiometry is a precisely tunable, purely sodium and chloride-based, three-dimensional bulk superconductor, which is therefore an ideal material for designing and understanding abnormal stoichiometric crystals. The methodology of constructing this bulk abnormal crystal may be general to almost all elements, which could lead to insights into the physics of other conventional superconductors and even high-critical-temperature superconductors.
分类: 物理学 >> 核物理学 提交时间: 2023-11-14
摘要: Two-body correlations of the isotope-resolved light and heavy clusters are measured in 86Kr+ 208Pb reactions at 25 MeV/u. The yield and kinetic variables of the A = 3 isobars, triton and 3He, are analyzed in coincidence with the heavy clusters of 7 A 14 emitted at the earlier chance. While the velocity spectra of both triton and 3He exhibit scaling behavior over the type of the heavy clusters, the yield ratios of t/ 3He correlate reversely to the neutron-to-proton ratio N/Z of the latter, showing the ping-pong modality of the N/Z of emitted clusters. The commonality that the N/Z of the residues keeps the initial system value is extended to the cluster emission in heavy ion reactions. The comparison of transport model calculations to the data is discussed.