分类: 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间: 2017-05-08
摘要: Stretchable and flexible conductive polymers have aroused great interest recently because of their applications in the fields of novel electronics, such as smart textiles, artificial electronic skin, flexible electronic displays, etc. In this work, stretchable and flexible conductive thermoplastic polyurethane (TPU)/graphene composite foams have been developed by water vapour induced phase separation. The as-prepared TPU/graphene composite foams exhibited a lower modulus, larger elongation at break, and lower hysteresis during a cycle tensile test than a TPU/graphene composite did. It is expected that the improved elasticity of the TPU/graphene composite foams was caused by the deformation of cells, which partially offset the deformation of the TPU matrix. In addition, the cell walls divided the whole composites into many small parts, which could further restrain plastic deformation of hard segment domains under deformation.
分类: 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间: 2017-05-02
摘要: The preparation of lightweight materials with electromagnetic interference-shielding effect- iveness higher than 30dB is critical for most industrial and consumer applications. Compounding polymer resin with conductive filler can generate excellent electromagnetic interference-shielding effectiveness but usually leads to a high-sample density, while the foaming of polymer composite suffers from the significant-reduced electromagnetic inter- ference-shielding effectiveness. In this study, polyetherimide composite foams with loading of 10–80 phr (parts per hundred of resins) nickel particles were fabricated to meet the gap. The polyetherimide/nickel composite foams possessed uniform cell structure and low- sample density such as 0.86 g/cm3 at 70 phr nickel. The coupling effects of gravity settle- ment and cell-structure solidification led to the formation of gradient distribution of nickel particles across the foams. The formed novel structure facilitated the enhancement of multi-reflection and multi-scattering among nickel particles and cells. As a consequence, polyetherimide/nickel foam with 70 phr nickel (PEIN70) possessed a high-electromagnetic interference shielding effectiveness of 86.7–106.5 dB over a frequency range of 50–3000MHz. When the sample density was considered, the specific electromagnetic interference shielding effectiveness of PEIN70 foam was as high as 121.3 dB/(g/cm3) at 1 GHz, which was higher than the reported electromagnetic interference-shielding materials. The excellent electromagnetic interference-shielding properties, lightweight, well-defined resin proper- ties ensure polyetherimide/nickel composite foams useful in many advanced applications.